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Asymmetric Organocatalysis (Topics in Current Chemistry)

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 | #5890654 in Books |  Springer |  2010-03-04 | Original language:English | PDF # 1 |  9.20 x1.10 x6.20l,1.75 | File type: PDF | 460 pages

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||0 of 0 people found the following review helpful.| Great!|By Mathew|Great book for the practitioner of organocatalysis.This book really puts the field in perspective. The best part about the book is the classification of reaction types which makes it tremendously useful for efforts at new reaction discovery.|0 of 0 people found the following review helpful.| had me at science|By chiral

As nucleophiles, simple alkenes are typically so unreactive that only highly active electrophiles, such as carbocations, peroxides, and halogens will react with them. For the generation of carbon-carbon bonds, milder methods will often be required. Fortunately, it is possible to increase the reactivity of alkene-type p-nucleophiles by introducing electron-donating substituents. Substitution of one H with an OH or OR gives an enol or a vinyl ether, which are already much ...

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