[PDF.50dc] Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B (Springer Theses)

Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B (Springer Theses)

[PDF.za74] Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B (Springer Theses)

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 |  Sun Xiao Yu |  2014-02-23 |  2014-08-11 | Original language:English | PDF # 1 |  9.25 x.56 x6.10l,.75 | File type: PDF | 222 pages

 | Total Synthesis of Plakortide E and Biomimetic Synthesis of Plakortone B Springer Theses

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In his thesis, Xiaoyu Sun conducts the first total synthesis of all possible stereoisomers of plakortide E and also confirms the absolute configuration of natural plakortide E. Xiaoyu Sun subsequently converts Plakortide E methyl ester to plakortone B in a biomimetic conversion. Construction and functionalization of cyclic peroxides are notoriously difficult due to the very low O-O bond dissociation energy. Plaktoride E is isolated from the Jamaican marine sponge platori...

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