[PDF.87rp] Synthesis and Original Reactivity of Copper and Gold Complexes: σ-Bond Coordination, Oxidative Addition, Migratory Insertion (Springer Theses)

Synthesis and Original Reactivity of Copper and Gold Complexes: σ-Bond Coordination, Oxidative Addition, Migratory Insertion (Springer Theses)

[PDF.qm27] Synthesis and Original Reactivity of Copper and Gold Complexes: σ-Bond Coordination, Oxidative Addition, Migratory Insertion (Springer Theses)

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 |  2016-11-04 |  2016-10-15 | Original language:English | PDF # 1 |  9.25 x.60 x6.10l, | File type: PDF | 224 pages

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This thesis addresses the coordination chemistry and reactivity of copper and gold complexes with a focus on the elucidation of (i) the metal-mediated activation of σ-bonds and (ii) the migratory insertion reaction. Both processes are of considerable importance in organometallic chemistry, but remain elusive for Cu and Au complexes. In this work, the author contributes significant advances: The first σ-SiH complexes of copper are experimentally and computationally char...

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