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S Sulfur-Nitrogen Compounds: Part 10a: Compounds with Sulfur of Oxidation Number II (Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition)

Norbert Baumann, Hans-Jürgen Fachmann, Reimund Jotter, Alfons Kubny




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 |  1994-12-22 | Original language:English | PDF # 1 |  .0 x.0 x.0l,.0 | File type: PDF | 324 pages

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This volume treats the acyclic sulfur(II)-nitrogen compounds with one-coordinate and two-coordinate sulfur. Sulfur imide (S=NH) and N-organyl-sulfur imides (S=NR) are unstable compounds which can be stabilized by coordination to transition metals or trapped, for example, by 2 + 4 cycloaddition with 1,3-butadiene. Among dithionitryl (1+) salts, only S=N=S +AsF6- has been studied extensively. Cycloaddition with alkenes and triple bond compounds produce 1,3,2-dithiazolium s...

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