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Organic Synthesis using Samarium Diiodide: A Practical Guide

David J Procter, Robert A Flowers, Troels Skrydstrup




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 | #5415206 in Books |  CRC Press |  2010-03-24 | Original language:English | PDF # 1 |  9.21 x.80 x6.14l,1.05 | File type: PDF | 214 pages

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Samarium diiodide is one of the most important reducing agents available to synthetic organic chemists. The lanthanide(II) reagent acts by single-electron transfer to organic substrates leading to the formation of both radical and/or anionic intermediates. The power of the reagent arises from its versatility - samarium diiodide can be used in processes ranging from functional group conversions to elaborate carbon-carbon bond-forming cyclization sequences that result in a...

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