[PDF.06gx] New Strategies for N-Heterocyclic Carbenes Catalyzed Annulations (Springer Theses)

New Strategies for N-Heterocyclic Carbenes Catalyzed Annulations (Springer Theses)

[PDF.nt46] New Strategies for N-Heterocyclic Carbenes Catalyzed Annulations (Springer Theses)

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 |  2016-12-22 | Original language:English | PDF # 1 |  9.21 x.38 x6.14l, | File type: PDF | 123 pages

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This thesis focuses on NHC-catalyzed annulation of nitroalkenes, enals and α,β-unsaturated carboxylic acids. (1) NHCs were found to be efficient catalysts for the [4+2] annulation of β-substituted nitroalkenes. The scope of Rauhut–Currier reaction was successfully extended to the most challenging β-substituted alkenes by this method; (2) Enals were successfully used for [4+2] annulations with azodicarboxylates catalyzed by NHC via γ-addition. Highly enantio...

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