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Gold-Catalyzed Cycloisomerization Reactions Through Activation of Alkynes: New Developments and Mechanistic Studies (Springer Theses)

Antoine Simonneau




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 |  2016-10-28 |  2016-09-10 | Original language:English | PDF # 1 |  9.25 x.63 x6.10l,.84 | File type: PDF | 245 pages

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Antoine Simonneau's thesis highlights the development of new cycloisomerization reactions through the activation of alkynes with gold complexes. First Simonneau describes 1,6-enynes and their direct conversion into allenes through 1,5-hydride or ester migration processes. The author and his team used appropriate propargylic functional groups to achieve this conversion. This study shows that O-tethered 1,6-enynes carrying a strained cycloalkane at the propargylic position...

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